Product ID:SV CALIBRATION STANDARD KIT, 48118
MSDS Date:03/16/1994
FSC:6630
NIIN:00N066610
MSDS Number: CBDSV

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

500 MG/KG

CAS: 86-74-8

RTECS: FF3150000

Fraction By Weight: 0.2%

OSHA PEL N/K

ACGIH TLV: N/K

1000 MG/KG

CAS: 103-33-3

RTECS: CN1400000

Fraction By Weight: 0.2%

OSHA PEL N/K

ACGIH TLV: N/K

BENZENE, 1,2,4-TRICHLORO-; (1,2,4-TRICHLOROBENZENE) (SARA

CAS: 120-82-1

RTECS: DC2100000

Fraction By Weight: 0.2%

OSHA PEL C, 5 PPM

ACGIH TLV: C, 5 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BENZENE, HEXACHLORO-; (HEXACHLOROBENZENE) (SARA 313)

CAS: 118-74-1

RTECS: DA2975000

Fraction By Weight: 0.2%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ETHANE, HEXACHLORO-; (HEXACHLOROETHANE) (SARA 313) (CERCLA)

CAS: 67-72-1

RTECS: KI4025000

Fraction By Weight: 0.2%

OSHA PEL S, 1 PPM

ACGIH TLV: S, 1 PPM, A2

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

NAPHTHALENE, 2-CHLORO; (2-CHLORONAPHTHALENE)

CAS: 91-58-7

RTECS: QJ2275000

Fraction By Weight: 0.2%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

BENZENE, O-DICHLORO; (1,2-DICHLOROBENZENE) (SARA 313)

CAS: 95-50-1

RTECS: CZ4500000

Fraction By Weight: 0.2%

OSHA PEL C 50 PPM

ACGIH TLV: 25 PPM/50 STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BENZENE, M-DICHLORO-; (1,3-DICHLOROBENZENE)(SARA 313)

CAS: 541-73-1

RTECS: CZ4499000

Fraction By Weight: 0.2%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BENZENE, P-DICHLORO-; (1,4-DICHLOROBENZENE)

CAS: 106-46-1

RTECS: CZ4550000

Fraction By Weight: 0.2%

OSHA PEL N/K

ACGIH TLV: N/K

TOLUENE, 2,4-DINITRO-; (2,4-DINITROTOLUENE) (SARA 313)

CAS: 121-14-2

RTECS: XT1575000

Fraction By Weight: 0.2%

OSHA PEL S, 1.5 MG/M3

ACGIH TLV: 0.15 MG/M3, A2

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TOLUENE, 2,6-DINITRO-; (2,6-DINITROTOLUENE) (SARA 313)

CAS: 606-20-2

RTECS: XT1925000

Fraction By Weight: 0.2%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

1,3-BUTADIENE, HEXACHLORO-; (HEXACHLOROBUTADIENE) (SARA

CAS: 87-68-3

RTECS: EJ0700000

Fraction By Weight: 0.2%

OSHA PEL 0.02 PPM

ACGIH TLV: S,0.02 PPM, A2

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

1,3-CYCLOPENTADIENE,1,2,3,4,5,5-HEXACHLORO-;

CAS: 77-47-4

RTECS: GY1225000

Fraction By Weight: 0.2%

OSHA PEL 0.01 PPM

ACGIH TLV: 0.01 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

2-CYCLOHEXEN-1-ON3,3,5,5-TRIMETHYL-; (ISOPHORONE) (CERCLA)

CAS: 78-59-1

RTECS: GW7700000

Fraction By Weight: 0.2%

OSHA PEL 25 PPM

ACGIH TLV: C 5 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

BENZENE, NITRO-; (NITROBENZENE) (SARA 302/313)

CAS: 98-95-3

RTECS: DA6475000

Fraction By Weight: 0.2%

OSHA PEL S, 1 PPM

ACGIH TLV: S, 1 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHANE, DICHLORO- (METHYLENE CHLORIDE) (SARA 313) (CERCLA)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 97-100%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM, A2

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

IARC MONOGRAPHS, SUPP. VOL 7, PG

RTECS: 9999999ZZ

ANTICIPATED TO BE CARCINOGEN.

RTECS: 9999999ZZ

CHLORIDE IS NOT BELIEVED TO POSE CARCIN

RTECS: 9999999ZZ

TO CO & CAN STRESS CARDIOVASCULAR SYS DUE TO

RTECS: 9999999ZZ

BEEN SHOWN TO PRDCE SIGNIFICANT INCREASE IN SALIVARY

RTECS: 9999999ZZ

OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD

RTECS: 9999999ZZ

EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR

RTECS: 9999999ZZ

TO CHLOROCARBONS .

RTECS: 9999999ZZ

NEVER TRY TO MAKE AN UNCONSCIOUS PERSON

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:MAY BE FATAL IF INHALED. HARMFUL IF
SWALLOWED. CNTNS MATL(S) KNOWN TO STATE OF CA TO CAUSE CANCER.
LACHRIMATION, IRRITS SKIN, DERM, HDCH, DIZZ, NARCOSIS, LIVER &
KIDNEY DMG. CHRONIC:SEVERAL INHAL STUD IES REPORTED BY NIOSH
REVEALED THAT TEST ANIMALS EXPOSED TO METHYLENE CHLORIDE CONCS AS
HIGH AS 10,000(EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE:IARC MONOGRAPHS,
SUPP, VOL 7, PG 56, 1987:GROUP 2B. 7TH ANNUAL RPT ON CARCINS.
1994:ANTIC TO (SUPDAT)
Effects of Overexposure:HLTH HAZS:PPM SHOWED SLIGHT LIVER & KIDNEY
CHANGES. METHYLENE CHLORIDE HAS BEEN SHOWN TO INCREASE RATE OF
SPONTANEOUSLY OCCURING MALIGNANT TUMORS IN ONE STRAIN OF LAB MICE &
BENIGN TUMORS IN LAB RATS. OTHER ANIMAL STUDIES, AS WELL AS
SEVERAL HUMAN EPIDEMIOLOGY STUDIES, HAVE INDICATED A NEG RESPONSE.
METHYLENE (ING 19)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR @ LST 15 MIN. SKIN:PROMPTLY WASH
W/MILD SOAP & LG VOLS OF WATER. REMOVE CONTAM CLTHG. INHAL:IMMED
MOVE TO FRESH AIR. GIVE OXYG IF BRTHG IS LABORED. IF BRTHG STOPS,
GIVE ARTF RES P. CONT MD. NEVER ADMIN ADRENALIN FOLLOWING CH*2CL*2
EXPOS. INCR SENSITIVITY OF HEART TO ADRENALIN MAY BE CAUSED BY
OVEREXP TO CH*2CL*2. INGEST:NEVER GIVE ANYTHING BY MOUTH TO UNCON
PERSON. (ING 25)

Lower Limits:12.0%
Upper Limits:19.0%
Extinguishing Media:WATER, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THE FOLLOWING TOXIC VAPORS ARE FORMED
WHEN THIS MATERIAL IS HEATED TO DECOMPOSITION:HYDROGEN CHLORIDE,
PHOSGENE, OXIDES OF NITROGEN.

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. METHYLENE CHLORIDE VAPORS ARE HEAVIER THAN AIR AND WILL
COLLECT IN LOW AREAS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER.
Other Precautions:POSSIBLE CANCER HAZARD. NO SMOKING IN AREA OF USE. DO
NOT USE IN THE GENERAL VICINITY OF ARC WELDING, OPEN FLAMES OR HOT
SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE THE FORMATION OF HCL
AND/OR PHOSGE NE .

Respiratory Protection:WEAR NIOSH/MSHA APPROVED FACE MASK WITH ORGANIC
VAPOR CANISTER. WEAR NIOSH/MSHA/OSHA APPPROVED RESPIRATORY
PROTECTION.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:WEAR NEOPRENE GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
HAZ DECOMP PRODS:ARCS CAN DECOMPOSE TO FORM HYDROGEN CHLORIDE GAS &
TRACES OF PHOSGENE. EXPLAN OF CARCIN:BE CARCIN. ANIMAL:LUNG, LIVER,
SALIVARY, MAMMARY GLAND (TUMORS). P-DICHLOROBENZENE:IARC MONOGRA
PHS, SUPP, VOL 7, PG 192, 1987:GROUP 2B. NTP 7TH ANNUAL RPT ON
CARCINS, 1994:ANTIC TO BE CARCIN. (ING 17)

Boiling Pt:B.P. Text:104F,40C
Melt/Freeze Pt:M.P/F.P Text:-143F,-97C
Vapor Pres:349 @ 20C
Vapor Density:2.93 @ 20C
Spec Gravity:1.320 (H*2O=1)
Evaporation Rate & Reference:0.71 (ETHER=1)
Solubility in Water:1.6
Appearance and Odor:CLEAR, COLORLESS LIQUID WITH AN ETHER-LIKE ODOR.
Percent Volatiles by Volume:10

Stability Indicator/Materials to Avoid:YES
STRONG BASES, OXIDIZING AGENTS. LIQ OXYG/OTHER STRONG OXIDANTS MAY FORM
EXPLO MIX W/METHYLENE CHLORIDE.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, OXIDES OF
NITROGEN. MATL/ITS VAPS WHEN IN CONT W/FLAMES, HOT GLOWING
SURFS/ELEC (SUPDAT)

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE OR
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.